Synthesis of an excellent MTP catalyst: hierarchical ZSM-5 zeolites with great mesoporosity
نویسندگان
چکیده
منابع مشابه
Adsorption of carbon monoxide in H-ZSM-5 and Li-ZSM-5 zeolites: an embedded ab initio cluster study
The absorption of carbon monoxide with H-ZSM-5 and metal-substituted Li-ZSM-5 zeolites has been investigated by Ž . using both cluster and embedded cluster approaches at the HFr6–31G d,p level of theory. For the H-ZSM-5 zeolite, the binding energy of CO on a 3T quantum cluster is predicted to be 2.25 kcalrmol for the C-bound complex. The O-bound complex was found to be less stable by about 0.84...
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Catalytic biomass conversion is often hindered by coking. Carbon compounds cover active surface and plug pores, causing catalyst deactivation. Material design at the nanoscale allows tailoring of the catalytic activity and stability. Here, we report a simple synthesis of nanosized ZSM-5 materials by using a silicalite-1 seeding suspension. ZSM-5 crystals were grown from a deionized silica sourc...
متن کاملMesoporosity--a new dimension for zeolites.
Frameworks of precisely defined pores with diameters matching the size of small molecules endow crystalline zeolites with valuable size- and shape-selectivity. Being important selective adsorbers and separators, zeolites are also indispensable as solid acids in size-selective catalysis. However, despite being extremely beneficial, micropores impose restrictions on the mass transport of reactant...
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چکیده ندارد.
Organosilane with gemini-type structure as the mesoporogen for synthesis of hierarchical porous ZSM-5 zeolite
A new kind of organosilane (1,6-bis (diethyl(3-trimethoxysilylpropyl)ammonium) hexane bromide) with a geminitype structure was prepared and used as a mesoporogen for the synthesis of hierarchical porous ZSM-5 zeolite. There are two quaternary ammonium centers along with double hydrolysable -RSi(OMe)3 fragments in the organosilane, which results in a strong interaction between this mesoporogen a...
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ژورنال
عنوان ژورنال: Royal Society Open Science
سال: 2018
ISSN: 2054-5703
DOI: 10.1098/rsos.181691